I once tried melting PLA together with this tool. It worked fairly straight forward: cut both filament ends in a 90° angle, put them in the guides, and keep them in place with two fingers. Heat a knife in a bunsen burner, and insert it in-between both ends. A soldering iron should also work. Slide the ends towards the knife or soldering iron, let them melt, remove knife/iron, and push molten ends together. Keep a while until cool. This goes easier than describing it. But then I had to cut off the inevitable flanges and smoothen these out with a cutter knife or Dremel-like tool. It worked well, but it takes so much time that it isn't worth the effort. But this technique could be usefull if you want a vase or toy with colors that change over and over, on a single nozzle printer.
So, now I use these ends for atomic pulls, like kmanstudios and several other people here.
If you have kids, you could soften these pieces, and make toys out of it, or wrist bands, etc.