Thanks Randy, much appreciated.
I have ordered one from Farnell here in the UK, the one he was looking at was 3mm rather than 2mm, so I was glad to find your post before he ordered the wrong one.
I had already tried most of this, the un-tinned ends was not something I tried, but I did loosen and re-tighten a couple of times. I will take that advice when I re-assemble.
I was really struggling to figure out what was going on until the PT100 failed altogether; so now it's pretty clear from measuring directly on the component. Initially I managed to get a reading on 108 Ohms, I couldn't get it consistently, but now I have a permanent open-circuit.
Thanks again,
Greg