The humidly of the room is low (under 30%) in the winter and but the spool has been out for several days.
The printer was left running at work, but I can see it stopped with an error, not sure why it stopped though. I have a PO in for some new spools of PVA and a drying solution.
It interesting that you say how PVA does not stick to PLA. I noticed that Cura left some 'cut outs' on the brim and I wondered why. From what you say it must be for the PVA to stick directly to the bed, however it did not adhere to the print bed well either.
I think my next step is going to be to clean everything, dry out the PVA and try again. I can deal with a little bit of stringiness, but if the prints won't finish thats going to be a problem.