PLA is the easiest material to print with. PVA is not even close. It's going to always be at least a little bit stringy. In general you want to keep it dry. PVA starts absorbing water as soon as you open the bag and the manufacturers don't necessarily dry the filament (some even run their filament through a water bath to cool it rapidly) but Ultimaker brand PVA is usually quite dry.
Within 24 hours of leaving the spool on the printer PVA should degrade.
Brittle sometimes means it is too dry but I suspect not in your case. PVA is brittle even when it's at the perfect dryness.
Instead - it looks like you printed PVA on top of brim. That is bad - PLA prints nicely on top of PVA but not the other way around. PVA does not print well on top of PLA. You need to increase the "support horizontal expansion" to a large enough value so it reaches the print bed. Only then will it stay on top of the PLA (because part of the PVA structure is anchored on the print bed to help hold it in place).
90% of the problems people have with PVA is because it got too wet. You can tell because you can see steam coming out of the nozzle as it prints. Do you have 2 gallon zip bags ready to store you PVA in? You need to do that ASAP. Just a few days in humid air and now you have to learn how to dry your PVA on the print bed. Also buy some color changing dessiccant - get a liter or so. I suspect you haven't had that issue yet and may not for a few weeks/months.
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Slashee_the_Cow 427
As a mere mortal with a much less expensive printer, I can't actually print PVA, but I can offer general advice.
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