Been printing rubber bungs for work all day yesterday and had a really bad headache all night! Got another full days printing ahead today.
There really needs to be a list generated for all the filament types along with there toxicity. This would allow us to identify which filaments require ventilation and which ones you can just leave a window open while printing.
Link to Material Safety Data Sheet for NinjaFlex - http://dzmlsvv5f118.cloudfront.net/wp-content/uploads/2013/11/MSDS-NinjaFlex.pdf?afe842
Here are some relevant extracts:
ACUTE TOXICITY:
IRRITATION/CORROSION: Not likely to result in irritation in solid form. Thermal decomposition may result in release of toxic airborne contaminates which can be irritating to eyes, skin and respiratory tract.
FIRST AID MEASURES:
INHALATION: Not likely to result in irritation in solid form. Thermal decomposition may result in release of toxic airborne contaminants. Remove exposed individual to fresh air and keep the person calm. Assist in breathing if necessary. Immediate medical attention required.
EXPOSURE CONTROLS / PERSONAL PROTECTION
VENTILATION: During fused deposition modeling operations, use with ventilation adequate to reduce levels of air contaminants below that which may cause personal injury or illness. Local exhaust ventilation that removes air contaminants from the breathing zone is preferred. General, mechanical, or dilution ventilation may be suitable.
RESPIRATORY PROTECTION: Wear a NIOSH-certified (or equivalent) organic vapor respirator as needed.
SKIN PROTECTION: Wear gloves when handling hot materials.
EYE/FACE PROTECTION: Wear splash goggles to protect from hot molten substance/product.
GENERAL: Wear protective clothing to prevent contact during hot melt conditions. When using, do not eat, drink or
smoke. After use wash hands with soap and water.
STABILITY AND REACTIVITY
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, hydrogen cyanide
THERMAL DECOMPOSITION: No decomposition if stored and handled as prescribed/indicated. Thermal decomposition above the indicated temperature is possible ( > 230 °C). Prolonged thermal loading can result in products of degradation being given off.
I really don't want to be a scaremonger here but I print this filament at 240 °C on my UM2! Organizing an extraction system as I type this!
As nallath points out there is no need to panic, but its well worth baring in mind the potential hazards associated with printing this and other filaments. We really do need to find out just how much of each type of fume is released in a "normal" printing scenario to asses the realistic dangers.