@gr5 thanks for this. I'm going through these settings and have so far noticed one discrepancy. My wall speeds were set to 45 mm/s, and only 20 mm/s on windows. Reducing to 20 has made an improvement - visually there are no longer the gaps that I was seeing previously.
However, the print quality is still significantly stronger on the windows print. The walls can still pop out on the mac print, but not the windows one.
Here's 2 images of the latest print. I'll continue to look through the settings.
https://www.dropbox.com/s/5dvncpzbc3k9k3h/FIX-ATTEMPT1-1.jpeg
https://www.dropbox.com/s/1lq2iwcu5qzwz19/FIX-ATTEMPT1-2.jpeg
Regarding defaults, I previously found that having z hop disabled by default caused a fair amount of issues, but I've no idea whether there are good reasons for that being set so.