I am also encountering the same 'centering' issue as Brassovits. I've set Cura to my Ender 3 Pro. I see that the Settings | Printer | Manage Printers | Machine Settings | Printer Settings are: X=220.0, Y=220.0, and Z=250.0 and the Extruder Settings on that same page are: Xmin= -26, Ymin = -32, Xmax = 32, Ymax = 34, Gantry Height = 25.
This is the first time I've tried to print something that extends nearly to the limits of the printable area (209 mm X 209 mm).
Yet, as you can see in the images, Cura places the print FAR to the front and left side of the print mat. This centering ultimately, I think, interferes with adherance to the mat where the heating element of the bed is 5 mm inset from the edge, causing the surface, there, to be too cool.
I'm printing with SunLu PLA+ Silk Black and don't have any experience with this product. I'm only guessing that the adherance problem is not actually a problem with the filament itself. The extruder temp is 220 C, Bed 60 C as recommended in the resources that I can find. So, there's that! (Whew, did someone say complicated?)
I know as stated above that "centering" is complicated. Is it possible for a genius to look at the numbers above and the photos and tell a novice like myself exactly what I might try to correct this and get the print centered?
Thanks,
Dave