The reason is that with bowden systems it is important to keep the flow of the nozzle constant. The moment you switch from printing the inner wall (at a higher speed, so higher flow) to the outer wall, you get a tiny bit of overextrusion.
In order to minimize that defect we first print all inner walls and then all outer walls (or vice versa, depending on settings)
Also it's not that simple to implement.
I've just made a small fix which makes the outer wall print first when you are using a brim: https://github.com/Ultimaker/CuraEngine/pull/486
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fma 2
I'm wondering: did you address this problem¹ in Cura 2.5.0-BETA?
Thanks,
¹ yes, this is really a problem! It messes up very small holes on first layer, and it also gives a much lower adhesion between walls, as the filament has time to cool down.
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