I have installed CURA 5.1.0 today and I experienced the same problem.
It worked with a model, but I got a "slicing error" after loading another STL file and then the slice button no longer appeared, even if I cleared all and reloaded the STL model.
Also solved by restarting CURA.
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highlander_kjm 0
I restarted Cura and it now works!
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