I agree that the black gunk is probably PLA that leaked long ago and slowly over many prints baked itself black. It is helping you by sealing any leaks. But there could be more black gunk inside which would be bad. Personally I would put the whole thing in an oven at 200C and then take a hot wire and clean it all out.
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nick-foley 5
I think it is just overcooked PLA ooze, but I'm not 100% sure. Something similar was happening to my ultimaker (and to get consistent prints, I had to keep raising the extrusion rate with each print, eventually reaching the point of stalled/ground filament).
...I then broke the brass tube trying to remove it from the PEEK. Even hot, it can be very challenging to remove because there is not a strong place to grab without crushing the tube. They should really make the round flange of the brass tube have two flats, so that you can grab it with a wrench without having to transfer force through the thermal break. (Actually, forget that - they should just redesign the entire hot end with less parts and fewer points of failure.)
I ended up fixing my machine with a Makergear tube and nozzle. Prints seem to be good so far but I don't think I've solved the problem entirely yet. If I were to do it again, the first thing I would do is try a new nozzle without messing with the rest of the setup. I don't know if it was the cause of the problem, but it's a simple, easy test that allows you to eliminate one variable from the equation for the rest of your troubleshooting.
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